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La valeur du rapport molaire donneur d'électron/alcoyl-aluminium qui présente la conductibilité électrique maximale dépend des empêchements stériques existants des deux côtés, ainsi que du nombre de groupes donneurs de la molécule du donneur d'électrons. Dans le cas des empêchements stériques petits ou modérés et d'un seul groupe de donneurs existants dans la molécule du donneur d'électrons, la conductibilité maximale doit apparaître pour un rapport molaire égal à l'unité, ou, en tout cas, proche à cette valeur.

I Rezina, 5, 3 (1966). 7. M. M. A G A E V et Y u . G. KORABLEV, AAzerb. Neft. 1 0 , 4 3 (1969). 8. M. M. A G A E V , Y U . G. KORABLEV, L. C. Y A S E N K A et V. F. EVSTRATOV, Kauch i Rezina 12, 6 (1969). 9. V. V. N A L I M O V et N . A . C E R N O V A , Staticeskie metodi planirovania extremalnih experimenîov. Moskva, Nauka, 1965. 53 Détermination gaz-chromatographique des oligomères du butadiene, produits secondaires dans le processus d'obtention du caoutchouc polybutadiénique ELENA C E A U S E S C U , VICTORIA FIEROIU, E C A T E R I N A f UDOR, N.

10 10 50 50 10 10 50 50 10 10 50 50 10 10 50 50 Cod. — — — + + + — — — — + + + + Nat. 30 30 30 30 90 90 90 90 30 30 30 30 90 90 90 90 Cod. — — — — — — — + + + + + + Nat. 20 20 20 20 20 20 20 20 40 40 40 40 40 40 40 40 Cod. V "* - Nat. 58 100 100 58 100 58 58 100 100 58 58 100 58 100 100 58 ML ( 1 + 4 ) 100°C 45,0 77,8 37,0 21,0 76,0 47,5 21,0 36,0 78,3 47,0 19,0 37,0 44,0 78,3 36,2 20,0 43,0 79,0 38,0 19,0 78,0 46,5 23,0 35,0 77,5 56,0 17,0 36,0 45,0 77,5 37,0 17,0 Par la suite de l'interprétation mathématique on a obtenu les valeurs numériques des coefficients du modèle qui décrit le processus dans le domaine étudié.

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