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For instance, a copper-ion Selectrode turned out to be more sensitive than an ISE previously produced. 5 mV, and the life-time is several months. Selectrodes with liquid ion exchangers and neutral carriers. Select­ rodes with liquid ion exchangers or chelates described by Ruzicka and coworkers [113,114,126,128] are easily prepared. Thus, a gra­ phite rod is impregnated by liquid exchangers under vacuum. In another method [119], a liquid exchanger is mixed with graphite powder and an insulating tube is filled with this mixture.

P a l k i n . M a t e r i a l s , 1§_, 22 (1980) 34. Trümpier. 35. Krukov. 51509 36. Thompson. 37. Pey. 38. Ershov. 39. Sergeev. Khim. (USSR) J52, 2487 (1979) 40. Stefanova. Universiteta N 4, 22 (1972); N 4, 81, 88 (1976) 41. Nikolaev. Fizika i Khimia Stekla (USSR) Ί_, 426 (1981); USSR Patent No. 759943 (1980) 42. Bubireva. 52 (1982); USSR Patent No. Electroch. N. USSR, Inorg. R. Khim. (USSR) 5»4, 830 (1981) 43. Grekovich. 44. Garbusova. Universiteta, N 16, 68 (1980) 45. Materova, in: "Ionnii obmen i ionometrija".

Therefore, the task of CWE improvement is of great importance. The creation of CWEs having entirely reproducible and sufficiently stable potential seems to be quite possible, and it is worth seeking a solution of this problem. , 6, 125 (1984) Solid Contact ISEs 5. 3P - salt solubility product in water phase and in membrane phase, respectively EMF - electromotive force e - electron z - ion charge /Λ· i - i-ion chemical potential A* l - i-ion electrochemical potential (j - membrane electric conduction E - electric conduction activation energy PVC - Polyvinylchloride Val - valinomycin DOP - dioctylphthalate TDA - tetradecylammonium CWE - coated wire electrode ISFET - ion-selective field effect transistor 6.

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