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The tendency of the rod segments to be arranged into anisotropic order along their axes seems to play an important role in liquid crystalline behavior of the polymer. 6,7 Because of the preferred parallel arrangement of the rigid, rodlike units, the formation of curved interfaces is strongly hindered in the mesogenic rods. On the contrary, rod-coil block systems based on mesogenic rods can provide a variety of supramolecular structures due to the effect of microphase separation and the molecular anisometry of rod block.

Copyright 1999 American Association for the Advancement of Science). 110 In contrast to the rod-coil diblock copolymers which exhibit multiple morphologies, the triblock copolymers were found to spontaneously form only microcapsules or spherical vesicles in solution as evidenced by optical polarized, fluorescence optical, and scanning electron microscopies (Figure 33). Supramolecular Structures from Rod−Coil Block Copolymers Figure 33. SEM image of microcapsules formed by 31 with n ) 250. (Reprinted with permission from ref 110.

D. degree in Macromolecular Science from Case Western Reserve University, Cleveland, in 1992. In the same year, he became a postdoctoral fellow at University of Illinois, Urbana-Champaign. In 1993, he was a senior research scientist at Korea Research Institute of Chemical Technology where he worked in the field of π-conjugated systems. In 1994, he joined the Faculty of Chemistry at Yonsei University, Korea, where he is presently Associate Professor of Chemistry. His current research interests include synthetic self-organizing macromolecules, controlled supramolecular architectures, and organic nanostructured materials.

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