By Tuncay Ozel

This thesis specializes in the electrochemical synthesis of multi-segmented nanowires. not like past paintings, which was once principally restricted to one-dimensional ameliorations, Tuncay Ozel provides a strategy, termed coaxial Lithography (COAL), which permits for the synthesis of coaxial nanowires in a parallel type with sub-10 nanometer answer in either the axial and radial dimensions. This paintings has considerably extended present artificial features with appreciate to fabrics generality and the power to tailor two-dimensional progress within the formation of core-shell constructions. those advancements have enabled basic and utilized experiences which have been no longer formerly attainable. The COAL approach increases the services of many researchers who're attracted to learning light-matter interactions, nanoparticle meeting, solution-dispersible nanoparticles and labels, semiconductor gadget physics and nanowire biomimetic probe coaching. The method and effects awarded during this thesis entice researchers in nanomaterial synthesis, plasmonics, biology, photovoltaics, and photocatalysis.

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Nicewarner-Pena, S. , Freeman, R. , Reiss, B. , Pena, D. , Walton, I. , et al. (2001). Submicrometer metallic barcodes. Science, 294, 137. 58. , Foo, M. , Arsenault, A. , Zacharia, N. , & Ozin, G. A. (2007). Hinged nanorods made using a chemical approach to flexible nanostructures. Nature Nanotechnology, 2, 565. 59. Banholzer, M. , Millstone, J. , Osberg, K. , & Mirkin, C. A. (2009). On-wire lithography: synthesis, encoding and biological applications. Nature Protocols, 4, 838. 60. , Banholzer, M.

E. R2/1) without the Au rod and (ii) the difference in the electric field within the PTh segment at λ2 and λ1 (directly related to the spectral overlap between the SPR band and the pure PTh PL spectrum). Recent experiments have demonstrated PL emission from pure nanorods that follows the far-field scattering pattern of the longitudinal nanorod SPR upon irradiation of either the transverse SPR, the interband transitions, or the longitudinal SPR itself [54]. However, the quantum yield of the nanorod emission is around 2 × 10−6 which is four orders of magnitude lower than the quantum yield of the emission of polythiophene systems, typically around 10−2–10−1 [55].

1997). Pressure/temperature phase diagrams and superlattices of organically functionalized metal nanocrystal monolayers: the influence of particle size, size distribution, and surface passivant. The Journal of Physical Chemistry B, 101, 189. 34. Liz-Marzán, L. , & Mulvaney, P. (1996). Synthesis of nanosized gold-silica core-shell particles. Langmuir, 12, 4329. 35. El-Sayed, M. A. (2001). Some interesting properties of metals confined in time and nanometer space of different shapes. Accounts of Chemical Research, 34, 257.

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