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Other diatomic chalcogenides do not seem to correlate as well. Barrow and Jevons 48 also obtained a reasonable (but nonlinear) correlation of DS with reduced mass. In 1953, Lippincott 49 tried to extend Barrow and Jevons correlation of DS with re to predict the potential energy surfaces for these diatomics. In 1962, Laud so showed that Lippincott's equation was not generally valid for predicting accurate potential energy surfaces. 5{DS[M2(g)] + DS[Y 2(g)]} (7) where M is Bi, Sb, or Te and Y is Se or Te.

Table 5 summarizes the photolysis conditions that have been used to produce and monitor Te atoms. 1,o) atoms have also reportedly been produced from CSez by high-frequency discharge 1Z and microwave discharge,13 the Se atoms, per se, were not monitored; their existence was surmised from secondary reactions. Likewise, Te(5 3 P Z ,l,O) atoms were reported but not monitored in the microwave discharge of TeC1 4 • 164 Thermal production is a potential source of Se and Te in selected electronic states, but it has been very slightly exploited.

Is' ;=: N ~ a n t'"' ;=: I:l. ::t ~ I:l s:: ~ ~ ~ :-. 8 nm) KAFS (780 nm) 4 I So 4 ISO OCSe + hv -. Se+CO OCSe + hv -. e 1976 1976 1978 1978 Vacuum uv photolysis (A = 110-200 nm). Quantum yield of Se(4 ISO) is 75% for A = 164-180 nm and 20% for A > 200 nm Vacuum uv photolysis (172 nm). Experiments demonstrated laser oscillation at 489 and 777 nm due to Se(4 1So) ~ 150 151 29 30 34 35 149 1978 a ~ ...... '" ~ 1S ~ ~ ~ ~ .... ;:s $:) ~ E' ;:s " ~ ~ Ultraviolet photolysis. Quantum about 70% Q '"0:;'~ 135 1965 Ultraviolet photolysis (A ~ 200 nm).

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