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P6rot b aCentro de Cat/tlisis Petrdleo y Petroquimica- Escuela de Quimica Facultad de Ciencias- Universidad Central de Venezuela Apartado Postal 47102, Los Chaguaramos, Caracas 1020A, Venezuela bLaboratoire de Catalyse en Chimie Organique UMR CNRS 6503 Facult6 des Sciences - Universit6 de Poitiers 40, avenue du Recteur Pineau, 86022 Poitiers Cedex, France CLaboratoire de Catalyse et Spectrochimie UMR CNRS 6506 I S M R A - Universit6 de Caen 6, boulevard du Mar6chal Juin, 14050 Caen, France dInstitut Frangais du P6trole 1 et 4, avenue de Bois Pr6au, 92852 Rueil-Malmaison Cedex, France HD isotopic exchange experiments carried out over sulfided catalysts showed that part of the exchangeable hydrogen measured by isotopic dilution came from the support and depended on the pretreatment conditions.

Clausen and H. Topsoe, J. , 187 (1999) 109. 18. P. Raybaud, J. Hafner, G. Kresse, S. Kazstelan and H. Toulhoat, J. , 190 (2000) 128. 19. V. Lauritsen, S. Helveg, E. La~gsgaard, I. S. Clausen, H. Topsoe and F. Besenbacher, J. , 197 (2001) 1. Studies in Surface Science and Catalysis 138 A. Guerrero-Ruiz and I. V. All rights reserved. In-situ FTIR study of hydrogen kinetics in hybrid catalysts 39 spillover and reaction Azfar Hassan, a Kaoru Fujimoto, b Keiichi Tomishige, b Toshiaki Kusakari b and Asuka Akasaka b a Center for Refining and Petrochemicals, Research Institute, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia.

S. Faraday Trans. I 76 (1980) 1585. 2. T. K. Hall, J. Phys. Chem. 95 (1991) 9966. 3. T. K. Hall, ibid. 96 (1992) 8131. 4. E. Massoth, J. Catal. 36 (1975) 164. 5. P. B. Moyes and J. Tomkinson, Bull. Soc. Chim. Belg. 100 (1991) 967. 6. C. Thomas, L. L. Lemberton, S. Kasztelan and G. P6rot, J. Catal. 167 (1997) 1. 7. C. Thomas, L. Vivier, A. Travert, F. Maug6, S. Kasztelan and G. P6rot, J. Catal. 179 (1998) 495. 8. C. Thomas, L. Vivier, M. Lescanne, S. Kasztelan and G. P6rot, Catal. Lett. 58 (1999) 33.

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