By W. B. Pearson and G. V. Raynor (Auth.)

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G. Brillouin zone overlaps in the aluminium latticef or incomplete ionization in In). D. values derived from solid solutions in Cu, Ag, Au, Mg, and Al. H. J. AXON and W. HUME-ROTHERY (1948) Proc. Roy. Soc. A193. 1. * For definition see p. 19. t See p. 53 for discussion. D. D. of the pure metals. D. values obtained for a solute in any particular solvent depended chiefly on four factors: (1) the Ve effect, which is the relative volume per valency electron of solvent and solute. D. D. of the solute.

An in­ crease of electron concentration in the tin solid solution would cause further overlap of these planes resulting in a contraction of the zone along the a axis and an expansion of the crystal in real space, agreeing with the decreasing axial ratio found in Sn-Sb and Sn-Bi alloys. It is not certain whether the (211) planes have also been overlapped, but this type of overlap would have a relatively small effect on the axial ratios. However, it seems probable from consideration of the vacant sites that occur in dilute solid solutions with In and Cd as solutes (Fig.

RAYNOR (1940-41) Proc. Roy. Soc. A177, 27. 54 THE THEORY OF ALLOYS N(E) curves derived by Μοττ and JONES (1936) suggested that an overlap of the (200) planes of energy discontinuity had occurred in pure Al. D.

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